CINECA IRIS Institutional Research Information System

L'autonomia finanziaria delle Regioni speciali tra prerogative statutarie e poteri legislativi statali

Synthesis of 2-acylindoles via Ag- and Cu-catalyzed anti-Michael hydroamination of β-(2-aminophenyl)-α,β-ynones: Experimental results and DFT calculation

β-2-aminophenyl)-α,β-ynones afforded 3-unsubstituted 2-acylindoles in good yields in the presence of 20 mol% of AgOTf under MW heating. The use CuOTf as catalyst resulted in a similar reaction outcome, generally with a lower efficiency. This transformation represents the first example of 5-e...

5-Exo-dig aminocylization/hydroxyfluorination of propargylic carbamates

The unprecedented annulation/hydroxyfluorination of propargylic carbamates to give 4-fluoromethyl-4-hydroxy-oxazolidinones was investigated. The reaction was effectively promoted by NaHCO3and/or silver catalysis. The peculiar behavior of propargylic carbamates bearing a chiral steroidal moiety is described. Extensions&#x...

Monitoring of the regulatory criteria for raw milk collected from dairy farms in Central Italy

The milk from dairy animals has a good nutritional value because it represents an indispensable source of high quality proteins. Moreover, it is the raw material for many dairy products consumed worldwide such as fresh and ripened cheeses, butter, cream and fermented derivatives li...